MetaCyc Pathway: indole glucosinolate activation (herbivore attack) in Cupriavidus basilensis FW507-4G11

Add experiment(s):


Thioglucosidase:
glucobrassicin + H2O→(indol-3-yl)-N-(sulfonatooxy)methanimidothioate + D-glucopyranose + H+ (EC 3.2.1.147)
No genes
(indol-3-yl)-N-(sulfonatooxy)methanimidothioate→indolylmethylisothiocyanate + sulfate (spontaneous)
No genes
(indol-3-yl)-N-(sulfonatooxy)methanimidothioate→(indol-3-yl)acetonitrile + sulfur(0) + sulfate (EC 4.8.1.5)
No genes
Nitrilase:
(indol-3-yl)acetonitrile + 2 H2O→(indol-3-yl)acetate + ammonium (EC 3.5.5.1)
RR42_RS05880
indolylmethylisothiocyanate→indole-3-carbinonium ion + isothiocyanate
No genes
(indol-3-yl)acetate→indole-3-carboxylate
No genes
indole-3-carbinonium ion + H2O→indole-3-carbinol + H+ (spontaneous)
No genes
indole-3-carbinonium ion + L-ascorbate→ascorbigen (spontaneous)
No genes
2 indole-3-carbinol→3,3'-di(indol-3-yl)methane + formaldehyde + H2O (spontaneous)
No genes
indole-3-carbinol + an oxidized electron carrier→indole-3-carbaldehyde + a reduced two electron carrier (spontaneous)
No genes
indole-3-carbinol + glutathione→indol-3-ylmethyl-glutathione + H2O (spontaneous)
No genes
indole-3-carbinol + L-cysteine→indol-3-ylmethyl-L-cysteine + H2O (spontaneous)
No genes
indole-3-carbaldehyde→indole-3-carboxylate
No genes

Links:

Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information