MetaCyc Pathway: 5-methoxybenzimidazolyl adenosylcobamide biosynthesis from adenosylcobinamide-GDP in Cupriavidus basilensis FW507-4G11

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Nicotinate-nucleotide--dimethylbenzimidazole phosphoribosyltransferase:
5-methoxybenzimidazole + β-nicotinate D-ribonucleotide→5-methoxybenzimidazole ribotide phosphate + nicotinate + H+ (EC 2.4.2.21)
RR42_RS16120
Adenosylcobinamide-GDP ribazoletransferase:
5-methoxybenzimidazole ribotide phosphate + adenosylcobinamide-GDP→Coα-[α-(5-methoxybenzimidazolyl)]-Coβ-adenosylcobamide 5'-phosphate + GMP + H+ (EC 2.7.8.26)
RR42_RS16115
Alpha-ribazole phosphatase:
Coα-[α-(5-methoxybenzimidazolyl)]-Coβ-adenosylcobamide 5'-phosphate + H2O→Coα-[α-(5-methoxybenzimidazolyl)]-Coβ-adenosylcobamide + phosphate (EC 3.1.3.73)
RR42_RS16110

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information