Chorismate lyase:
chorismate→4-hydroxybenzoate + pyruvate (EC 4.1.3.40) |
| RR42_RS17665 |
| L-proline + ATP + a holo-[Bmp1 prolyl-carrier protein]→an L-prolyl-[Bmp1 prolyl-carrier protein] + AMP + diphosphate (EC 6.2.1.53) |
| No genes |
| 4-hydroxybenzoate + bromide + NADPH + dioxygen + 2 H+→3-bromo-4-hydroxybenzoate + NADP+ + 2 H2O (EC 1.14.19.55) |
| No genes |
| an L-prolyl-[Bmp1 prolyl-carrier protein] + 2 an oxidized electron-transfer flavoprotein + H+→a 1H-pyrrole-2-carbonyl-[Bmp1 prolyl-carrier protein] + 2 a reduced electron-transfer flavoprotein (EC 1.3.8.14) |
| No genes |
| 3-bromo-4-hydroxybenzoate + bromide + NADPH + dioxygen + 3 H+→2,4-dibromophenol + CO2 + NADP+ + 2 H2O (EC 1.14.19.55) |
| No genes |
| a 1H-pyrrole-2-carbonyl-[Bmp1 prolyl-carrier protein] + bromide + FADH2 + dioxygen→a 5-bromo-1H-pyrrole-2-carbonyl-[Bmp1 prolyl-carrier protein] + FAD + 2 H2O (EC 1.14.19.57) |
| No genes |
| 2 2,4-dibromophenol + dioxygen + 2 H+ + 2 a reduced ferredoxin [iron-sulfur] cluster→2,6-dibromo-4-(2,4-dibromophenoxy)phenol + 2 an oxidized ferredoxin [iron-sulfur] cluster + 2 H2O (EC 1.14.19.M18) |
| No genes |
| a 5-bromo-1H-pyrrole-2-carbonyl-[Bmp1 prolyl-carrier protein] + bromide + FADH2 + dioxygen→a 4,5-dibromo-1H-pyrrole-2-carbonyl-[Bmp1 prolyl-carrier protein] + FAD + 2 H2O (EC 1.14.19.57) |
| No genes |
| 2 2,4-dibromophenol + dioxygen + 3 H+ + 4 a reduced ferredoxin [iron-sulfur] cluster→2-bromo-4-(2,4-dibromophenoxy)phenol + bromide + 4 an oxidized ferredoxin [iron-sulfur] cluster + 2 H2O (EC 1.14.19.M18) |
| No genes |
| 2 2,4-dibromophenol + dioxygen + 3 H+ + 4 a reduced ferredoxin [iron-sulfur] cluster→4',4,6-tribromo-2,2-biphenol + bromide + 4 an oxidized ferredoxin [iron-sulfur] cluster + 2 H2O (EC 1.14.19.M18) |
| No genes |
| 2 2,4-dibromophenol + dioxygen + H+ + 2 a reduced ferredoxin [iron-sulfur] cluster→3,3',5,5'-tetrabromo-2,2'-biphenyldiol + 2 an oxidized ferredoxin [iron-sulfur] cluster + 2 H2O (EC 1.14.19.M18) |
| No genes |
| 2,4-dibromophenol + bromide + NADPH + dioxygen + H+→2,4,6-tribromophenol + NADP+ + 2 H2O (EC 1.14.19.55) |
| No genes |
| 2 2,4-dibromophenol + dioxygen + H+ + 2 a reduced ferredoxin [iron-sulfur] cluster→2,4-dibromo-6-(2,4-dibromophenoxy)phenol + 2 an oxidized ferredoxin [iron-sulfur] cluster + 2 H2O (EC 1.14.19.M18) |
| No genes |
| a 4,5-dibromo-1H-pyrrole-2-carbonyl-[Bmp1 prolyl-carrier protein] + bromide + FADH2 + dioxygen→a 3,4,5-tribromo-1H-pyrrole-2-carbonyl-[Bmp1 prolyl-carrier protein] + FAD + 2 H2O (EC 1.14.19.57) |
| No genes |
| 2 2,4,6-tribromophenol + dioxygen + 5 H+ + 4 a reduced ferredoxin [iron-sulfur] cluster→2,6-dibromo-4-(2,4,6-tribromophenoxy)phenol + bromide + 4 an oxidized ferredoxin [iron-sulfur] cluster + 2 H2O (EC 1.14.19.M18) |
| No genes |
| a 3,4,5-tribromo-1H-pyrrole-2-carbonyl-[Bmp1 prolyl-carrier protein] + H2O→tribromopyrrole-2-carboxylate + a holo-[Bmp1 prolyl-carrier protein] + H+ |
| No genes |
| tribromopyrrole-2-carboxylate + H+→2,3,4-tribromo-1H-pyrrole + CO2 |
| No genes |
| 2 2,3,4-tribromo-1H-pyrrole + dioxygen + 2 H+ + 2 a reduced ferredoxin [iron-sulfur] cluster→hexabromo-2,2'-bipyrrole + 2 an oxidized ferredoxin [iron-sulfur] cluster + 2 H2O (EC 1.14.19.M18) |
| No genes |
| 2,4-dibromophenol + 2,3,4-tribromo-1H-pyrrole + dioxygen + H+ + 2 a reduced ferredoxin [iron-sulfur] cluster→pentabromopseudilin + 2 an oxidized ferredoxin [iron-sulfur] cluster + 2 H2O (EC 1.14.19.M18) |
| No genes |
| pentabromopseudilin→2,3,5,7-tetrabromobenzofuro[3,2-b]pyrrole + bromide (spontaneous) |
| No genes |
Links:
Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information