MetaCyc Pathway: p-HBAD biosynthesis in Cupriavidus basilensis FW507-4G11

Add experiment(s):


Chorismate lyase:
chorismate→4-hydroxybenzoate + pyruvate (EC 4.1.3.40)
RR42_RS17665
4-hydroxybenzoate + S-adenosyl-L-methionine→methylparaben + S-adenosyl-L-homocysteine (EC 2.1.1.M17)
No genes
methylparaben + dTDP-β-L-rhamnose→4-O-(α-L-rhamnopyranosyl)-hydroxybenzoate methyl ester + H+ + dTDP (EC 2.4.1.M3)
No genes
4-O-(α-L-rhamnopyranosyl)-hydroxybenzoate methyl ester + S-adenosyl-L-methionine→p-HBAD-I + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.M13)
No genes
p-HBAD-I + dTDP-β-L-rhamnose→O-methyl-4-O-[α-L-rhamnopyranosyl-(1→3)-2-O-methyl-α-L-rhamnopyranosyl]-hydroxybenzoate + H+ + dTDP (EC 2.4.1.M4)
No genes
O-methyl-4-O-[α-L-rhamnopyranosyl-(1→3)-2-O-methyl-α-L-rhamnopyranosyl]-hydroxybenzoate + GDP-β-L-fucose→O-methyl-4-O-[α-L-fucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-2-O-methyl-α-L-rhamnopyranosyl]-hydroxybenzoate + GDP + H+ (EC 2.4.1.M5)
No genes
O-methyl-4-O-[α-L-fucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-2-O-methyl-α-L-rhamnopyranosyl]-hydroxybenzoate + S-adenosyl-L-methionine→O-methyl-4-O-[2-O-methyl-α-L-fucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-2-O-methyl-α-L-rhamnopyranosyl]-hydroxybenzoate + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.M14)
No genes
O-methyl-4-O-[2-O-methyl-α-L-fucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-2-O-methyl-α-L-rhamnopyranosyl]-hydroxybenzoate + S-adenosyl-L-methionine→O-methyl-4-O-[2,4-di-O-methyl-α-L-fucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-2-O-methyl-α-L-rhamnopyranosyl]-hydroxybenzoate + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.M15)
No genes
O-methyl-4-O-[2,4-di-O-methyl-α-L-fucopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-2-O-methyl-α-L-rhamnopyranosyl]-hydroxybenzoate + S-adenosyl-L-methionine→p-HBAD-II + S-adenosyl-L-homocysteine + H+ (EC 2.1.1.M16)
No genes

Links:

Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information