MetaCyc Pathway: Spodoptera littoralis pheromone biosynthesis in Cupriavidus basilensis FW507-4G11

Add experiment(s):


palmitoyl-CoA[in] + an oxidized electron-transfer flavoprotein[in] + H+[in]→(2E)-hexadec-2-enoyl-CoA[in] + a reduced electron-transfer flavoprotein[in] (EC 1.3.8.9)
No genes
Enoyl-CoA hydratase (in reverse):
(2E)-hexadec-2-enoyl-CoA + H2O→(S)-3-hydroxyhexadecanoyl-CoA
(EC 4.2.1.17)
RR42_RS00730
RR42_RS02510
RR42_RS02525
RR42_RS03015
RR42_RS04550
RR42_RS05755
RR42_RS05760
RR42_RS07510
RR42_RS10250
RR42_RS10265
RR42_RS10270
RR42_RS11095
RR42_RS12500
RR42_RS12795
RR42_RS13545
RR42_RS16175
RR42_RS16790
RR42_RS18250
RR42_RS18255
RR42_RS19805
RR42_RS19815
RR42_RS22630
RR42_RS22680
RR42_RS23295
RR42_RS23450
RR42_RS23710
RR42_RS24355
RR42_RS24895
RR42_RS25480
RR42_RS25525
RR42_RS25900
RR42_RS28050
RR42_RS28325
RR42_RS28330
RR42_RS28425
RR42_RS28545
RR42_RS28550
RR42_RS29425
RR42_RS29465
RR42_RS29940
RR42_RS29945
RR42_RS31580
RR42_RS31675
RR42_RS31935
RR42_RS31945
RR42_RS34175
RR42_RS34180
RR42_RS34905
RR42_RS35130
RR42_RS35270
RR42_RS36335
RR42_RS36495
Delta(11)-fatty-acid desaturase:
palmitoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(11Z)-hexadecenoyl-CoA + 2 a ferricytochrome b5 + 2 H2O
(EC 1.14.19.5)
No genes
Long-chain-3-hydroxyacyl-CoA dehydrogenase:
(S)-3-hydroxyhexadecanoyl-CoA + NAD+→3-oxopalmitoyl-CoA + NADH + H+
(EC 1.1.1.211)
RR42_RS02510
RR42_RS05760
RR42_RS10265
RR42_RS11095
RR42_RS22630
RR42_RS28325
RR42_RS29465
RR42_RS31050
RR42_RS35270
(11Z)-hexadecenoyl-CoA[in] + an oxidized electron-transfer flavoprotein[in] + H+[in]→(2E,11Z)-hexadec-2,11-dienoyl-CoA[in] + a reduced electron-transfer flavoprotein[in] (EC 1.3.8.9)
No genes
Acetyl-CoA C-myristoyltransferase (in reverse):
3-oxopalmitoyl-CoA + coenzyme A→myristoyl-CoA + acetyl-CoA
(EC 2.3.1.155)
RR42_RS00885
RR42_RS11085
RR42_RS16595
RR42_RS22625
RR42_RS37020
Enoyl-CoA hydratase (in reverse):
(2E,11Z)-hexadec-2,11-dienoyl-CoA + H2O→(3S,11Z)-3-hydroxyhexadec-11-enoyl-CoA
(EC 4.2.1.17)
RR42_RS00730
RR42_RS02510
RR42_RS02525
RR42_RS03015
RR42_RS04550
RR42_RS05755
RR42_RS05760
RR42_RS07510
RR42_RS10250
RR42_RS10265
RR42_RS10270
RR42_RS11095
RR42_RS12500
RR42_RS12795
RR42_RS13545
RR42_RS16175
RR42_RS16790
RR42_RS18250
RR42_RS18255
RR42_RS19805
RR42_RS19815
RR42_RS22630
RR42_RS22680
RR42_RS23295
RR42_RS23450
RR42_RS23710
RR42_RS24355
RR42_RS24895
RR42_RS25480
RR42_RS25525
RR42_RS25900
RR42_RS28050
RR42_RS28325
RR42_RS28330
RR42_RS28425
RR42_RS28545
RR42_RS28550
RR42_RS29425
RR42_RS29465
RR42_RS29940
RR42_RS29945
RR42_RS31580
RR42_RS31675
RR42_RS31935
RR42_RS31945
RR42_RS34175
RR42_RS34180
RR42_RS34905
RR42_RS35130
RR42_RS35270
RR42_RS36335
RR42_RS36495
myristoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(11E)-tetradecenoyl-CoA + 2 a ferricytochrome b5 + 2 H2O (EC 1.14.19.24)
No genes
Delta(11)-fatty-acid desaturase:
myristoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(11Z)-tetradecenoyl-CoA + 2 a ferricytochrome b5 + 2 H2O
(EC 1.14.19.5)
No genes
Long-chain-3-hydroxyacyl-CoA dehydrogenase:
(3S,11Z)-3-hydroxyhexadec-11-enoyl-CoA + NAD+→(11Z)-3-oxohexadecenoyl-CoA + NADH + H+
(EC 1.1.1.211)
No genes
myristoyl-CoA + 2 NADPH + 2 H+→tetradecan-1-ol + coenzyme A + 2 NADP+ (EC 1.2.1.84)
No genes
(11E)-tetradecenoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(9Z,11E)-tetradec-9,11-dienoyl-CoA + 2 a ferricytochrome b5 + 2 H2O
No genes
(11Z)-tetradecenoyl-CoA + 2 NADPH + 2 H+→(11Z)-tetradecenol + coenzyme A + 2 NADP+ (EC 1.2.1.84)
No genes
(11E)-tetradecenoyl-CoA + 2 NADPH + 2 H+→(11E)-tetradecenol + coenzyme A + 2 NADP+ (EC 1.2.1.84)
No genes
Acetyl-CoA C-myristoyltransferase (in reverse):
(11Z)-3-oxohexadecenoyl-CoA + coenzyme A→(9Z)-tetradecenoyl-CoA + acetyl-CoA
(EC 2.3.1.155)
No genes
tetradecan-1-ol + acetyl-CoA→tetradecan-1-yl acetate + coenzyme A
No genes
(9Z,11E)-tetradec-9,11-dienoyl-CoA + 2 NADPH + 2 H+→(9Z,11E)-tetradeca-9,11-dien-1-ol + coenzyme A + 2 NADP+ (EC 1.2.1.84)
No genes
(11Z)-tetradecenol + acetyl-CoA→(11Z)-tetradecen-1-yl acetate + coenzyme A
No genes
(9Z)-tetradecenoyl-CoA + 2 NADPH + 2 H+→(9Z)-tetradecenol + coenzyme A + 2 NADP+ (EC 1.2.1.84)
No genes
(11E)-tetradecenol + acetyl-CoA→(11E)-tetradecen-1-yl acetate + coenzyme A
No genes
(9Z,11E)-tetradeca-9,11-dien-1-ol + acetyl-CoA→(9Z,11E)-tetradeca-9,11-dien-1-yl acetate + coenzyme A
No genes
(9Z)-tetradecenol + acetyl-CoA→(9Z)-tetradecen-1-yl acetate + coenzyme A
No genes

Links:

Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information