MetaCyc Pathway: rhizocticin A and B biosynthesis in Cupriavidus basilensis FW507-4G11

Add experiment(s):


Phosphoenolpyruvate mutase:
phosphoenolpyruvate + H+→3-phosphonopyruvate (EC 5.4.2.9)
RR42_RS22445
Phosphonopyruvate decarboxylase:
3-phosphonopyruvate + H+→phosphonoacetaldehyde + CO2 (EC 4.1.1.82)
RR42_RS22450
phosphonoacetaldehyde + oxaloacetate + H+→2-keto-4-hydroxy-5-phosphopentanoate + CO2
No genes
2-keto-4-hydroxy-5-phosphopentanoate→2-keto-5-phospho-3-cis-pentenoate + H2O
No genes
2-keto-4-hydroxy-5-phosphopentanoate + an L-amino acid→2-amino-4-hydroxy-5-phosphonopentanoate + a 2-oxo carboxylate
No genes
2-keto-5-phospho-3-cis-pentenoate + an L-amino acid→L-2-amino-5-phosphono-3-cis-pentenoate + a 2-oxo carboxylate
No genes
2-amino-4-hydroxy-5-phosphonopentanoate + L-arginine + ATP→L-arginyl-4-hydroxy-5-phosphonopentanoate + ADP + H+ + phosphate
No genes
2-amino-4-hydroxy-5-phosphonopentanoate→L-2-amino-5-phosphono-3-cis-pentenoate + H2O
No genes
L-arginyl-4-hydroxy-5-phosphonopentanoate + ATP + L-valine→L-valyl-L-arginyl-4-hydroxy-5-phosphonopentanoate + ADP + H+ + phosphate
No genes
L-2-amino-5-phosphono-3-cis-pentenoate + L-arginine + ATP→rhizocticin A + ADP + H+ + phosphate
No genes
L-valyl-L-arginyl-4-hydroxy-5-phosphonopentanoate→rhizocticin B + H2O
No genes
rhizocticin A + ATP + L-valine→rhizocticin B + ADP + H+ + phosphate
No genes

Links:

Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information