Stearoyl-CoA 9-desaturase:
palmitoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→palmitoleoyl-CoA + 2 a ferricytochrome b5 + 2 H2O (EC 1.14.19.1) |
| RR42_RS17025 |
Delta(12)-fatty-acid desaturase:
palmitoleoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(9Z,12Z)-hexadeca-9,12-dienoyl-CoA + 2 a ferricytochrome b5 + 2 H2O (EC 1.14.19.6) |
| No genes |
| (9Z,12Z)-hexadeca-9,12-dienoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(9Z,12Z,15Z)-hexadeca-9,12,15-trienoyl-CoA + 2 a ferricytochrome b5 + 2 H2O (EC 1.14.19.13) |
| No genes |
| (9Z,12Z,15Z)-hexadeca-9,12,15-trienoyl-CoA + 3 malonyl-CoA + 3 H+→5-pentadecatrienyl resorcinol + 4 CO2 + 4 coenzyme A |
| No genes |
| 5-pentadecatrienyl resorcinol + S-adenosyl-L-methionine→5-pentadecatrienyl resorcinol-3-methyl ether + S-adenosyl-L-homocysteine + H+ |
| No genes |
| 5-pentadecatrienyl resorcinol-3-methyl ether + dioxygen + a reduced [NADPH-hemoprotein reductase]→dihydrosorgoleone + an oxidized [NADPH-hemoprotein reductase] + H2O |
| No genes |
| dihydrosorgoleone + a methylated methyl acceptor→methoxydihydrosorgoleone + a demethylated methyl acceptor |
| No genes |
| dihydrosorgoleone + dioxygen→sorgoleone + H+ + H2O (spontaneous) |
| No genes |
Links:
Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information