MetaCyc Pathway: sesamin biosynthesis in Cupriavidus basilensis FW507-4G11

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Laccase:
4 coniferyl alcohol + dioxygen→4 coniferyl alcohol radical + 2 H2O (EC 1.10.3.2)
No genes
Peroxidase:
2 coniferyl alcohol + hydrogen peroxide→2 coniferyl alcohol radical + 2 H2O (EC 1.11.1.7)
RR42_RS16550
RR42_RS26270
2 coniferyl alcohol radical→(+)-pinoresinol
No genes
(+)-pinoresinol + dioxygen + a reduced [NADPH-hemoprotein reductase]→(+)-piperitol + an oxidized [NADPH-hemoprotein reductase] + 2 H2O (EC 1.14.19.74)
No genes
(+)-piperitol + dioxygen + a reduced [NADPH-hemoprotein reductase]→(+)-sesamin + an oxidized [NADPH-hemoprotein reductase] + 2 H2O (EC 1.14.19.74)
No genes
2 (+)-piperitol + dioxygen→2 (+)-sesamolinol
No genes
1.-.-.-:
2 (+)-sesamolinol + dioxygen→2 (+)-sesamolin + 2 H2O
No genes
1.-.-.-:
2 (+)-sesamin + dioxygen→2 (+)-sesamolin
No genes

Links:

Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information