MetaCyc Pathway: toyocamycin biosynthesis in Rhodospirillum rubrum S1H

preQ0 + 5-phospho-α-D-ribose 1-diphosphate→5-phospho-α-D-ribose-1-preQ0 + diphosphate

No genes

5-phospho-α-D-ribose-1-preQ0 + NADPH + 2 H+→[(1R,2R,3S,4S)-4-{5-cyano-4-oxo-3H-pyrrolo[2,3-d]pyrimidin-7-yl}-2,3-dihydroxycyclopentyl]methyl phosphate + ammonium + NADP+

Rru_A1958

[(1R,2R,3S,4S)-4-{5-cyano-4-oxo-3H-pyrrolo[2,3-d]pyrimidin-7-yl}-2,3-dihydroxycyclopentyl]methyl phosphate + GTP + L-aspartate→succinylo-toyocamycin phosphate + GDP + 2 H+ + phosphate

Rru_A1964

succinylo-toyocamycin phosphate→toyocamycin phosphate + fumarate

Rru_A0716

toyocamycin phosphate + H2O→toyocamycin + phosphate

No genes

Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information