Pentachlorophenol monooxygenase:
pentachlorophenol + NADPH + dioxygen + H+→2,3,5,6-tetrachloro-1,4-benzoquinone + chloride + NADP+ + H2O (EC 1.14.13.50) |
| No genes |
| 2,3,5,6-tetrachloro-1,4-benzoquinone + NADH→2,3,5,6-tetrachlorohydroquinone + NAD+ + H+ (EC 1.1.1.404) |
| JOY50_RS03560 |
| 2,3,5,6-tetrachlorohydroquinone + glutathione + H+→2,3,5-trichloro-6-(glutathion-S-yl)-hydroquinone + chloride (EC 1.21.4.5; 2.5.1.18) |
| JOY50_RS01335 |
| JOY50_RS02075 |
| JOY50_RS03220 |
| JOY50_RS04640 |
| JOY50_RS05060 |
| JOY50_RS06505 |
| JOY50_RS06895 |
| JOY50_RS15060 |
| JOY50_RS15545 (maiA) |
| JOY50_RS15840 |
| JOY50_RS18765 |
| JOY50_RS24510 (yghU) |
| 2,3,5-trichloro-6-(glutathion-S-yl)-hydroquinone + glutathione→2,3,6-trichlorohydroquinone + glutathione disulfide + H+ (EC 1.21.4.5; 1.8.5.7) |
| No genes |
| 2,3,6-trichlorohydroquinone + glutathione→2,6-dichloro-3-(glutathion-S-yl)-hydroquinone + chloride (EC 1.21.4.5; 2.5.1.18) |
| JOY50_RS01335 |
| JOY50_RS02075 |
| JOY50_RS03220 |
| JOY50_RS04640 |
| JOY50_RS05060 |
| JOY50_RS06505 |
| JOY50_RS06895 |
| JOY50_RS15060 |
| JOY50_RS15545 (maiA) |
| JOY50_RS15840 |
| JOY50_RS18765 |
| JOY50_RS24510 (yghU) |
| 2,6-dichloro-3-(glutathion-S-yl)-hydroquinone + glutathione→2,6-dichlorohydroquinone + glutathione disulfide + H+ (EC 1.21.4.5; 1.8.5.7) |
| No genes |
| 2,6-dichlorohydroquinone + dioxygen + H2O→2-chloromaleylacetate + chloride + 2 H+ |
| No genes |
Maleylacetate reductase (in reverse):
2-chloromaleylacetate + NAD(P)H + H+→5-chloro-3-oxoadipate + NAD(P)+ (EC 1.3.1.32) |
| No genes |
| 5-chloro-3-oxoadipate→2-maleylacetate + chloride + H+ (spontaneous) |
| No genes |
Maleylacetate reductase (in reverse):
2-maleylacetate + NAD(P)H + H+→3-oxoadipate + NAD(P)+ (EC 1.3.1.32) |
| JOY50_RS07690 |
| JOY50_RS07855 |
Links:
Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information