Limonene 1,2-monooxygenase:
(4R)-limonene + NAD(P)H + dioxygen + H+→a (4R)-1,2-epoxymenth-8-ene + NAD(P)+ + H2O (EC 1.14.13.107) |
| Rv3618 |
Limonene-1,2-epoxide hydrolase:
a (4R)-1,2-epoxymenth-8-ene + H2O→(1S,2S,4R)-limonene-1,2-diol (EC 3.3.2.8) |
| Rv2740 |
| (1S,2S,4R)-limonene-1,2-diol + a mycofactocinone→(1S,4R)-1-hydroxymenth-8-en-2-one + a mycofactocinol |
| No genes |
Limonene-1,2-diol dehydrogenase:
(1S,2S,4R)-limonene-1,2-diol + NAD+→(1S,4R)-1-hydroxymenth-8-en-2-one + NADH + H+ (EC 1.1.1.297) |
| No genes |
Monocyclic monoterpene ketone monooxygenase:
(1S,4R)-1-hydroxymenth-8-en-2-one + NADPH + dioxygen + H+→(4R)-7-hydroxy-4-isoprenyl-7-methyl-2-oxo-oxepanone + NADP+ + H2O (EC 1.14.13.105) |
| No genes |
Monocyclic monoterpene ketone monooxygenase:
(4R)-7-hydroxy-4-isoprenyl-7-methyl-2-oxo-oxepanone→(3R)-3-isopropenyl-6-oxoheptanoate + H+ (spontaneous) (EC 1.14.13.105) |
| No genes |
| (3R)-3-isopropenyl-6-oxoheptanoate + ATP + coenzyme A→(3R)-3-isopropenyl-6-oxoheptanoyl-CoA + ADP + phosphate |
| No genes |
Links:
Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information