MetaCyc Pathway: petroselinate biosynthesis in Sphingomonas koreensis DSMZ 15582

Add experiment(s):


a palmitoyl-[acp] + dioxygen + 2 H+ + 2 a reduced ferredoxin [iron-sulfur] cluster→a (4Z)-hexadec-4-enoyl-[acp] + 2 an oxidized ferredoxin [iron-sulfur] cluster + 2 H2O (EC 1.14.19.11)
No genes
Beta-ketoacyl-acyl-carrier-protein synthase II:
a (4Z)-hexadec-4-enoyl-[acp] + a malonyl-[acp] + H+→a (6Z)-3-oxooctadec-6-enoyl-[acp] + a soluble [acyl-carrier protein] + CO2 (EC 2.3.1.179)
Ga0059261_0362
3-oxoacyl-[acyl-carrier-protein] reductase (in reverse):
a (6Z)-3-oxooctadec-6-enoyl-[acp] + NADPH + H+→a (3R,6Z)-3-hydroxyoctadec-6-enoyl-[acp] + NADP+ (EC 1.1.1.100)
Ga0059261_0364
Ga0059261_0812
Ga0059261_0843
Ga0059261_0844
Ga0059261_0867
Ga0059261_1325
Ga0059261_1787
Ga0059261_1900
Ga0059261_1968
Ga0059261_2637
Ga0059261_2655
Ga0059261_2665
Ga0059261_2801
Ga0059261_2802
Ga0059261_2830
Ga0059261_2841
Ga0059261_2843
Ga0059261_2846
Ga0059261_2853
Ga0059261_2871
Ga0059261_2872
Ga0059261_2882
Ga0059261_2906
Ga0059261_4067
a (3R,6Z)-3-hydroxyoctadec-6-enoyl-[acp]→a (2E,6Z)-octadecadienoyl-[acp] + H2O
No genes
a (2E,6Z)-octadecadienoyl-[acp] + NADPH + H+→a petroselinoyl-[acp] + NADP+
No genes
Oleoyl-[acyl-carrier-protein] hydrolase:
a petroselinoyl-[acp] + H2O→petroselinate + a soluble [acyl-carrier protein] + H+ (EC 3.1.2.14)
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information