MetaCyc Pathway: limonene degradation II (L-limonene) in Caulobacter crescentus NA1000

Add experiment(s):


Limonene 1,2-monooxygenase:
(4S)-limonene + NAD(P)H + dioxygen + H+→a (4S)-1,2-epoxymenth-8-ene + NAD(P)+ + H2O
(EC 1.14.13.107)
No genes
Limonene-1,2-epoxide hydrolase:
a (4S)-1,2-epoxymenth-8-ene + H2O→(1R,2R,4S)-limonene-1,2-diol
(EC 3.3.2.8)
CCNA_03056
(1R,2R,4S)-limonene-1,2-diol + a mycofactocinone→(1R,4S)-1-hydroxymenth-8-en-2-one + a mycofactocinol
No genes
Limonene-1,2-diol dehydrogenase:
(1R,2R,4S)-limonene-1,2-diol + NAD+→(1R,4S)-1-hydroxymenth-8-en-2-one + NADH + H+
(EC 1.1.1.297)
No genes
Monocyclic monoterpene ketone monooxygenase:
(1R,4S)-1-hydroxymenth-8-en-2-one + NADPH + dioxygen + H+→(4S)-7-hydroxy-4-isoprenyl-7-methyl-2-oxo-oxepanone + NADP+ + H2O
(EC 1.14.13.105)
No genes
Monocyclic monoterpene ketone monooxygenase:
(4S)-7-hydroxy-4-isoprenyl-7-methyl-2-oxo-oxepanone→(3S)-3-isopropenyl-6-oxoheptanoate + H+
(spontaneous) (EC 1.14.13.105)
No genes
(3S)-3-isopropenyl-6-oxoheptanoate + ATP + coenzyme A→(3S)-3-isopropenyl-6-oxoheptanoyl-CoA + ADP + phosphate
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information