MetaCyc Pathway: Spodoptera littoralis pheromone biosynthesis in Paraburkholderia bryophila 376MFSha3.1

Add experiment(s):


palmitoyl-CoA[in] + an oxidized electron-transfer flavoprotein[in] + H+[in]→(2E)-hexadec-2-enoyl-CoA[in] + a reduced electron-transfer flavoprotein[in] (EC 1.3.8.9)
No genes
Enoyl-CoA hydratase (in reverse):
(2E)-hexadec-2-enoyl-CoA + H2O→(S)-3-hydroxyhexadecanoyl-CoA
(EC 4.2.1.17)
H281DRAFT_00361
H281DRAFT_00373
H281DRAFT_00653
H281DRAFT_00756
H281DRAFT_00916
H281DRAFT_01137
H281DRAFT_01179
H281DRAFT_01187
H281DRAFT_01199
H281DRAFT_01200
H281DRAFT_01276
H281DRAFT_01670
H281DRAFT_01774
H281DRAFT_02068
H281DRAFT_02497
H281DRAFT_02514
H281DRAFT_02515
H281DRAFT_02677
H281DRAFT_02741
H281DRAFT_02927
H281DRAFT_03491
H281DRAFT_03701
H281DRAFT_03739
H281DRAFT_03908
H281DRAFT_04594
H281DRAFT_04595
H281DRAFT_04625
H281DRAFT_04627
H281DRAFT_04744
H281DRAFT_05516
H281DRAFT_05722
H281DRAFT_05725
H281DRAFT_05977
Delta(11)-fatty-acid desaturase:
palmitoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(11Z)-hexadecenoyl-CoA + 2 a ferricytochrome b5 + 2 H2O
(EC 1.14.19.5)
No genes
Long-chain-3-hydroxyacyl-CoA dehydrogenase:
(S)-3-hydroxyhexadecanoyl-CoA + NAD+→3-oxopalmitoyl-CoA + NADH + H+
(EC 1.1.1.211)
H281DRAFT_00361
H281DRAFT_00916
H281DRAFT_03517
H281DRAFT_04595
H281DRAFT_04625
(11Z)-hexadecenoyl-CoA[in] + an oxidized electron-transfer flavoprotein[in] + H+[in]→(2E,11Z)-hexadec-2,11-dienoyl-CoA[in] + a reduced electron-transfer flavoprotein[in] (EC 1.3.8.9)
No genes
Acetyl-CoA C-myristoyltransferase (in reverse):
3-oxopalmitoyl-CoA + coenzyme A→myristoyl-CoA + acetyl-CoA
(EC 2.3.1.155)
H281DRAFT_00917
H281DRAFT_02089
Enoyl-CoA hydratase (in reverse):
(2E,11Z)-hexadec-2,11-dienoyl-CoA + H2O→(3S,11Z)-3-hydroxyhexadec-11-enoyl-CoA
(EC 4.2.1.17)
H281DRAFT_00361
H281DRAFT_00373
H281DRAFT_00653
H281DRAFT_00756
H281DRAFT_00916
H281DRAFT_01137
H281DRAFT_01179
H281DRAFT_01187
H281DRAFT_01199
H281DRAFT_01200
H281DRAFT_01276
H281DRAFT_01670
H281DRAFT_01774
H281DRAFT_02068
H281DRAFT_02497
H281DRAFT_02514
H281DRAFT_02515
H281DRAFT_02677
H281DRAFT_02741
H281DRAFT_02927
H281DRAFT_03491
H281DRAFT_03701
H281DRAFT_03739
H281DRAFT_03908
H281DRAFT_04594
H281DRAFT_04595
H281DRAFT_04625
H281DRAFT_04627
H281DRAFT_04744
H281DRAFT_05516
H281DRAFT_05722
H281DRAFT_05725
H281DRAFT_05977
myristoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(11E)-tetradecenoyl-CoA + 2 a ferricytochrome b5 + 2 H2O (EC 1.14.19.24)
No genes
Delta(11)-fatty-acid desaturase:
myristoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(11Z)-tetradecenoyl-CoA + 2 a ferricytochrome b5 + 2 H2O
(EC 1.14.19.5)
No genes
Long-chain-3-hydroxyacyl-CoA dehydrogenase:
(3S,11Z)-3-hydroxyhexadec-11-enoyl-CoA + NAD+→(11Z)-3-oxohexadecenoyl-CoA + NADH + H+
(EC 1.1.1.211)
No genes
myristoyl-CoA + 2 NADPH + 2 H+→tetradecan-1-ol + coenzyme A + 2 NADP+ (EC 1.2.1.84)
No genes
(11E)-tetradecenoyl-CoA + 2 a ferrocytochrome b5 + dioxygen + 2 H+→(9Z,11E)-tetradec-9,11-dienoyl-CoA + 2 a ferricytochrome b5 + 2 H2O
No genes
(11Z)-tetradecenoyl-CoA + 2 NADPH + 2 H+→(11Z)-tetradecenol + coenzyme A + 2 NADP+ (EC 1.2.1.84)
No genes
(11E)-tetradecenoyl-CoA + 2 NADPH + 2 H+→(11E)-tetradecenol + coenzyme A + 2 NADP+ (EC 1.2.1.84)
No genes
Acetyl-CoA C-myristoyltransferase (in reverse):
(11Z)-3-oxohexadecenoyl-CoA + coenzyme A→(9Z)-tetradecenoyl-CoA + acetyl-CoA
(EC 2.3.1.155)
No genes
tetradecan-1-ol + acetyl-CoA→tetradecan-1-yl acetate + coenzyme A
No genes
(9Z,11E)-tetradec-9,11-dienoyl-CoA + 2 NADPH + 2 H+→(9Z,11E)-tetradeca-9,11-dien-1-ol + coenzyme A + 2 NADP+ (EC 1.2.1.84)
No genes
(11Z)-tetradecenol + acetyl-CoA→(11Z)-tetradecen-1-yl acetate + coenzyme A
No genes
(9Z)-tetradecenoyl-CoA + 2 NADPH + 2 H+→(9Z)-tetradecenol + coenzyme A + 2 NADP+ (EC 1.2.1.84)
No genes
(11E)-tetradecenol + acetyl-CoA→(11E)-tetradecen-1-yl acetate + coenzyme A
No genes
(9Z,11E)-tetradeca-9,11-dien-1-ol + acetyl-CoA→(9Z,11E)-tetradeca-9,11-dien-1-yl acetate + coenzyme A
No genes
(9Z)-tetradecenol + acetyl-CoA→(9Z)-tetradecen-1-yl acetate + coenzyme A
No genes

Links:

Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information