MetaCyc Pathway: benzoate biosynthesis I (CoA-dependent, β-oxidative) in Burkholderia phytofirmans PsJN

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Phenylalanine ammonia-lyase:
L-phenylalanine→trans-cinnamate + ammonium
(EC 4.3.1.24; 4.3.1.25; 5.4.3.10)
No genes
trans-cinnamate + ATP + coenzyme A→(E)-cinnamoyl-CoA + AMP + diphosphate
No genes
Enoyl-CoA hydratase (in reverse):
(E)-cinnamoyl-CoA + H2O→(S)-3-hydroxy-3-phenylpropanoyl-CoA
(EC 4.2.1.17)
BPHYT_RS02345
BPHYT_RS03225
BPHYT_RS03235
BPHYT_RS03825
BPHYT_RS06755
BPHYT_RS06760
BPHYT_RS08375
BPHYT_RS08630
BPHYT_RS09560
BPHYT_RS10815
BPHYT_RS11780
BPHYT_RS13345
BPHYT_RS13545
BPHYT_RS14830
BPHYT_RS17335
BPHYT_RS17350
BPHYT_RS20025
BPHYT_RS25360
BPHYT_RS25695
BPHYT_RS27105
BPHYT_RS27895
BPHYT_RS28015
BPHYT_RS28020
BPHYT_RS28620
BPHYT_RS35465
3-hydroxyacyl-CoA dehydrogenase:
(S)-3-hydroxy-3-phenylpropanoyl-CoA + NAD+→3-oxo-3-phenylpropanoyl-CoA + NADH + H+
(EC 1.1.1.35)
BPHYT_RS03225
BPHYT_RS06760
BPHYT_RS09560
BPHYT_RS13545
BPHYT_RS34155
Acetyl-CoA C-acyltransferase (in reverse):
3-oxo-3-phenylpropanoyl-CoA + coenzyme A→benzoyl-CoA + acetyl-CoA
(EC 2.3.1.16)
BPHYT_RS02230
BPHYT_RS03230
BPHYT_RS08275
BPHYT_RS09150
BPHYT_RS09180
BPHYT_RS09565
BPHYT_RS17345
BPHYT_RS21955
BPHYT_RS29385
benzoyl-CoA + H2O→benzoate + coenzyme A + H+
BPHYT_RS35455
benzoyl-CoA + benzyl alcohol→benzyl benzoate + coenzyme A (EC 2.3.1.196)
No genes
benzyl benzoate + H2O→benzoate + benzyl alcohol + H+
No genes
Benzoate--CoA ligase:
benzoate + ATP + coenzyme A→benzoyl-CoA + AMP + diphosphate
(EC 6.2.1.25)
BPHYT_RS13365

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information