MetaCyc Pathway: benzoate biosynthesis III (CoA-dependent, non-β-oxidative) in Xanthomonas campestris pv. campestris strain 8004

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Reactions and Genes Citric Acid 16.67 mM (C)
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Phenylalanine ammonia-lyase:
L-phenylalanine→trans-cinnamate + ammonium (EC 4.3.1.24; 4.3.1.25; 5.4.3.10)
No genes
trans-cinnamate + ATP + coenzyme A→(E)-cinnamoyl-CoA + AMP + diphosphate
No genes
Enoyl-CoA hydratase (in reverse):
(E)-cinnamoyl-CoA + H2O→(S)-3-hydroxy-3-phenylpropanoyl-CoA (EC 4.2.1.17)
Xcc-8004.2740.1 -1.3
Xcc-8004.3347.1 N.D.
Xcc-8004.3683.1 -0.4
Xcc-8004.3686.1 +2.6
Xcc-8004.3687.1 +1.1
Xcc-8004.3832.1 -0.9
Xcc-8004.4248.1 +0.3
(S)-3-hydroxy-3-phenylpropanoyl-CoA→benzaldehyde + acetyl-CoA
No genes
Benzaldehyde dehydrogenase (NAD(+)):
benzaldehyde + NAD+ + H2O→benzoate + NADH + 2 H+ (EC 1.2.1.28)
Xcc-8004.464.1 +0.0

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information