MetaCyc Pathway: limonene degradation IV (anaerobic) in Herbaspirillum seropedicae SmR1

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Reactions and Genes Carbon source 2-Deoxyadenosine 5-monophosphate 2.5 mM
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limonene + an oxidized electron carrier + H2O→perillyl alcohol + a reduced two electron carrier (EC 1.17.99.8)
No genes
Perillyl-alcohol dehydrogenase:
perillyl alcohol + NAD+→perillyl aldehyde + NADH + H+
(EC 1.1.1.144)
No genes
Aldehyde dehydrogenase (NAD(+)):
perillyl aldehyde + NAD+ + H2O→perillate + NADH + 2 H+
(EC 1.2.1.3)
HSERO_RS04810 -0.2
HSERO_RS05115 -3.5
HSERO_RS05710 +0.1
HSERO_RS09465 -0.5
HSERO_RS11260 -0.1
HSERO_RS17620 +0.3
HSERO_RS19755 +0.0
HSERO_RS20590 +0.2
HSERO_RS20635 -0.1
HSERO_RS23860 -0.0
perillate + ATP + coenzyme A→perillyl-CoA + AMP + diphosphate (EC 6.2.1.M31)
No genes
perillyl-CoA + H2O→2-hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA
No genes
2-hydroxy-4-isopropenylcyclohexane-1-carboxyl-CoA + NAD+→2-oxo-4-Isopropenylcyclohexane-1-carboxyl-CoA + NADH + H+
No genes
2-oxo-4-Isopropenylcyclohexane-1-carboxyl-CoA + H2O→4-(isopropenyl)pimeloyl-CoA + H+
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information