MetaCyc Pathway: 4-ethylphenol degradation (anaerobic) in Rhodopseudomonas palustris CGA009

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Reactions and Genes 4-Hydroxybenzoate (C)
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1-ethyl-4-hydroxybenzene + an oxidized electron carrier + H2O→S-1-(4-hydroxyphenyl)-ethanol + a reduced two electron carrier
No genes
S-1-(4-hydroxyphenyl)-ethanol + NAD+→4-hydroxyacetophenone + NADH + H+
TX73_004045 -0.0
4-hydroxyacetophenone + ATP + CO2 + 2 H2O→4-hydroxybenzoyl-acetate + AMP + 3 H+ + 2 phosphate
No genes
4-hydroxybenzoyl-acetate + ATP + coenzyme A→3-(4-hydroxyphenyl)-3-oxo-propanoyl-CoA + AMP + diphosphate
No genes
Acetyl-CoA C-acyltransferase (in reverse):
3-(4-hydroxyphenyl)-3-oxo-propanoyl-CoA + coenzyme A→4-hydroxybenzoyl-CoA + acetyl-CoA (EC 2.3.1.16)
TX73_002660 -0.3
TX73_002750 -0.6
TX73_004215 +0.0
TX73_008765 +0.2
TX73_011915 +0.2
TX73_017920 +0.0
TX73_017940 -0.0
TX73_019245 +0.0
TX73_022530 +0.0
4-hydroxybenzoyl-CoA + 2 H+ + a reduced 2[4Fe-4s] ferredoxin→benzoyl-CoA + an oxidized 2[4Fe-4s] ferredoxin + H2O (EC 1.1.7.1)
TX73_003470 -6.0
TX73_003475 -4.6
TX73_003480 -4.5

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information