MetaCyc Pathway: benzoate biosynthesis III (CoA-dependent, non-β-oxidative) in Rhodopseudomonas palustris CGA009

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Reactions and Genes 4-Hydroxybenzoate (C)
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Phenylalanine ammonia-lyase:
L-phenylalanine→trans-cinnamate + ammonium (EC 4.3.1.24; 4.3.1.25; 5.4.3.10)
No genes
trans-cinnamate + ATP + coenzyme A→(E)-cinnamoyl-CoA + AMP + diphosphate
No genes
Enoyl-CoA hydratase (in reverse):
(E)-cinnamoyl-CoA + H2O→(S)-3-hydroxy-3-phenylpropanoyl-CoA (EC 4.2.1.17)
TX73_001990 +0.1
TX73_002165 -0.0
TX73_002395 -0.1
TX73_002500 +0.5
TX73_002510 +0.3
TX73_003370 +0.0
TX73_003500 +0.2
TX73_004220 +0.3
TX73_004930 -0.1
TX73_006355 -0.1
TX73_007240 +0.1
TX73_008780 -0.1
TX73_008810 +0.1
TX73_009040 -0.1
TX73_009055 -0.1
TX73_009075 +0.2
TX73_009185 +0.1
TX73_009315 +2.1
TX73_011065 +0.2
TX73_011975 -0.2
TX73_014325 -0.2
TX73_017085 -0.3
TX73_017810 +0.1
TX73_017840 +2.2
TX73_017875 -0.4
TX73_019255 -0.3
TX73_019650 -0.0
TX73_022390 -0.0
TX73_022490 +0.3
(S)-3-hydroxy-3-phenylpropanoyl-CoA→benzaldehyde + acetyl-CoA
No genes
Benzaldehyde dehydrogenase (NAD(+)):
benzaldehyde + NAD+ + H2O→benzoate + NADH + 2 H+ (EC 1.2.1.28)
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information