MetaCyc Pathway: caffeine degradation IV (bacteria, via demethylation and oxidation) in Pseudomonas fluorescens SBW25-INTG

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Reactions and Genes Guanosine 10 mM (C)
remove
caffeine + NAD(P)H + dioxygen + H+→theobromine + formaldehyde + NAD(P)+ + H2O (EC 1.14.13.178)
No genes
theobromine + dioxygen + H2O→3,7-dimethylurate + hydrogen peroxide
No genes
caffeine + NAD(P)H + dioxygen + H+→paraxanthine + formaldehyde + NAD(P)+ + H2O (EC 1.14.13.179)
No genes
theobromine + NAD(P)H + dioxygen + H+→7-methylxanthine + formaldehyde + NAD(P)+ + H2O (EC 1.14.13.179)
No genes
paraxanthine + NAD(P)H + dioxygen + H+→7-methylxanthine + formaldehyde + NAD(P)+ + H2O (EC 1.14.13.178)
No genes
paraxanthine + dioxygen + H2O→1,7-dimethylurate + hydrogen peroxide
No genes
7-methylxanthine + NAD(P)H + dioxygen + H+→xanthine + formaldehyde + NAD(P)+ + H2O (EC 1.14.13.128)
No genes
7-methylxanthine + dioxygen + H2O→7-methylurate + hydrogen peroxide
No genes
Xanthine dehydrogenase:
xanthine + NAD+ + H2O→urate + NADH + H+ (EC 1.17.1.4)
PFLU_RS22500 -2.8
PFLU_RS22505 -2.6
PFLU_RS26280 +0.0
PFLU_RS26285 -0.2
Xanthine oxidase:
xanthine + dioxygen + H2O→urate + hydrogen peroxide (EC 1.17.3.2)
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information