MetaCyc Pathway: 1,5-anhydrofructose degradation in Sinorhizobium meliloti 1021

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Reactions and Genes Mannobiose (C)
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1,5-anhydro-D-fructose reductase (1,5-anhydro-D-mannitol-forming) (in reverse):
1,5-anhydro-D-fructose + NAD(P)H + H+→1,5-anhydro-D-mannitol + NAD(P)+ (EC 1.1.1.292)
SMc04400 -0.3
Unspecific monooxygenase:
1,5-anhydro-D-mannitol + dioxygen + a reduced [NADPH-hemoprotein reductase]→D-mannopyranose + an oxidized [NADPH-hemoprotein reductase] + H2O (EC 1.14.14.1)
SMc01812 +0.1
Mannokinase:
D-mannopyranose + ATP→D-mannopyranose 6-phosphate + ADP + H+ (EC 2.7.1.7)
SMc03109 -5.3
Mannose-6-phosphate isomerase:
D-mannopyranose 6-phosphate→β-D-fructofuranose 6-phosphate (EC 5.3.1.8)
SMc03111 -6.4
Glucose-6-phosphate isomerase (in reverse):
β-D-fructofuranose 6-phosphate→α-D-glucose 6-phosphate (EC 5.3.1.9)
SM_b20857 -0.1
SMc02042 +0.2
SMc02163 N.D.

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information