MetaCyc Pathway: pyrethrin I biosynthesis in Paraburkholderia sabiae LMG 24235

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Chrysanthemyl diphosphate synthase:
2 prenyl diphosphate→(R,R)-chrysanthemyl diphosphate + diphosphate (EC 2.5.1.67)
No genes
(9S,13S,15Z)-12-oxophyto-10,15-dienoate→(S)-pyrethrolone
No genes
(R,R)-chrysanthemyl diphosphate + H2O→(R,R)-chrysanthemol + diphosphate
No genes
(R,R)-chrysanthemol + NAD+→(R,R)-chrysanthemal + NADH + H+
No genes
(R,R)-chrysanthemal + NAD(P)+ + H2O→(R,R)-chrysanthemate + NAD(P)H + 2 H+
QEN71_RS11670
(R,R)-chrysanthemate + ATP + coenzyme A→(R,R)-chrysanthemoyl CoA + AMP + diphosphate
No genes
(S)-pyrethrolone + (R,R)-chrysanthemoyl CoA→pyrethrin I + coenzyme A
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information