Pentachlorophenol monooxygenase:
pentachlorophenol + NADPH + dioxygen + H+→2,3,5,6-tetrachloro-1,4-benzoquinone + chloride + NADP+ + H2O (EC 1.14.13.50) |
| QEN71_RS16690 |
| 2,3,5,6-tetrachloro-1,4-benzoquinone + NADH→2,3,5,6-tetrachlorohydroquinone + NAD+ + H+ (EC 1.1.1.404) |
| No genes |
| 2,3,5,6-tetrachlorohydroquinone + glutathione + H+→2,3,5-trichloro-6-(glutathion-S-yl)-hydroquinone + chloride (EC 1.21.4.5; 2.5.1.18) |
| QEN71_RS00955 |
| QEN71_RS01655 |
| QEN71_RS05335 |
| QEN71_RS05570 |
| QEN71_RS07235 |
| QEN71_RS07950 |
| QEN71_RS09680 |
| QEN71_RS13620 |
| QEN71_RS14980 |
| QEN71_RS15945 |
| QEN71_RS16090 |
| QEN71_RS16255 |
| QEN71_RS16280 |
| QEN71_RS17320 |
| QEN71_RS18225 |
| QEN71_RS23535 |
| QEN71_RS24015 |
| QEN71_RS24045 |
| QEN71_RS26755 |
| QEN71_RS28625 |
| QEN71_RS37945 |
| QEN71_RS38990 |
| QEN71_RS39195 |
| QEN71_RS39455 |
| QEN71_RS39725 |
| 2,3,5-trichloro-6-(glutathion-S-yl)-hydroquinone + glutathione→2,3,6-trichlorohydroquinone + glutathione disulfide + H+ (EC 1.21.4.5; 1.8.5.7) |
| No genes |
| 2,3,6-trichlorohydroquinone + glutathione→2,6-dichloro-3-(glutathion-S-yl)-hydroquinone + chloride (EC 1.21.4.5; 2.5.1.18) |
| QEN71_RS00955 |
| QEN71_RS01655 |
| QEN71_RS05335 |
| QEN71_RS05570 |
| QEN71_RS07235 |
| QEN71_RS07950 |
| QEN71_RS09680 |
| QEN71_RS13620 |
| QEN71_RS14980 |
| QEN71_RS15945 |
| QEN71_RS16090 |
| QEN71_RS16255 |
| QEN71_RS16280 |
| QEN71_RS17320 |
| QEN71_RS18225 |
| QEN71_RS23535 |
| QEN71_RS24015 |
| QEN71_RS24045 |
| QEN71_RS26755 |
| QEN71_RS28625 |
| QEN71_RS37945 |
| QEN71_RS38990 |
| QEN71_RS39195 |
| QEN71_RS39455 |
| QEN71_RS39725 |
| 2,6-dichloro-3-(glutathion-S-yl)-hydroquinone + glutathione→2,6-dichlorohydroquinone + glutathione disulfide + H+ (EC 1.21.4.5; 1.8.5.7) |
| No genes |
| 2,6-dichlorohydroquinone + dioxygen + H2O→2-chloromaleylacetate + chloride + 2 H+ |
| No genes |
Maleylacetate reductase (in reverse):
2-chloromaleylacetate + NAD(P)H + H+→5-chloro-3-oxoadipate + NAD(P)+ (EC 1.3.1.32) |
| No genes |
| 5-chloro-3-oxoadipate→2-maleylacetate + chloride + H+ (spontaneous) |
| No genes |
Maleylacetate reductase (in reverse):
2-maleylacetate + NAD(P)H + H+→3-oxoadipate + NAD(P)+ (EC 1.3.1.32) |
| QEN71_RS19510 |
| QEN71_RS38175 |
Links:
Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information