MetaCyc Pathway: virginiae butanolide type γ-butyrolactones biosynthesis in Azospirillum sp. SherDot2

Add experiment(s):


glycerone phosphate + a medium-chain 3-oxoacyl-[acp]→a 2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate + a soluble holo-[acyl-carrier protein] (EC 2.3.1.277)
No genes
a 2-oxo-3-(phosphooxy)propyl 3-oxoalkanoate + H2O→a 3-hydroxy-2-oxopropyl 3-oxoalkanoate + phosphate
No genes
a 3-hydroxy-2-oxopropyl 3-oxoalkanoate→a 4-(hydroxymethyl)-3-(5-alkanoyl)-5H-furan-2-one + H2O
No genes
a 4-(hydroxymethyl)-3-(5-alkanoyl)-5H-furan-2-one + NADH + H+→an A-factor type γ-butyrolactone + NAD+ (EC 1.3.1.M14)
No genes
an A-factor type γ-butyrolactone + NADPH + H+→a VB type γ-butyrolactone + NADP+ (EC 1.1.1.413)
MPMX19_01147

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information