MetaCyc Pathway: dTDP-sibirosamine biosynthesis in Echinicola vietnamensis KMM 6221, DSM 17526

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Reactions and Genes L-tyrosine (N)
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Glucose-1-phosphate thymidylyltransferase:
α-D-glucopyranose 1-phosphate + H+ + dTTP→dTDP-α-D-glucose + diphosphate (EC 2.7.7.24)
Echvi_1740 N.D.
Echvi_2361 N.D.
dTDP-glucose 4,6-dehydratase:
dTDP-α-D-glucose→dTDP-4-dehydro-6-deoxy-α-D-glucopyranose + H2O (EC 4.2.1.46)
Echvi_2328 -2.0
Echvi_2329 N.D.
Echvi_3799 -0.2
Echvi_3804 +0.2
dTDP-4-dehydrorhamnose 3,5-epimerase:
dTDP-4-dehydro-6-deoxy-α-D-glucopyranose→dTDP-4-dehydro-β-L-rhamnose (EC 5.1.3.13)
Echvi_1151 N.D.
dTDP-4-dehydro-β-L-rhamnose + S-adenosyl-L-methionine→dTDP-4-dehydro-3-methyl-β-L-rhamnose + S-adenosyl-L-homocysteine + H+
No genes
dTDP-4-dehydro-3-methyl-β-L-rhamnose + L-glutamate→dTDP-4-amino-4-deoxy-3-methyl-β-L-rhamnose + 2-oxoglutarate
No genes
dTDP-4-amino-4-deoxy-3-methyl-β-L-rhamnose + S-adenosyl-L-methionine→dTDP-sibirosamine + S-adenosyl-L-homocysteine + H+
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information