MetaCyc Pathway: felinine and 3-methyl-3-sulfanylbutan-1-ol biosynthesis in Pseudomonas simiae WCS417

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Reactions and Genes D-Glucosamine Hydrochloride (C)
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3-(glutathion-S-yl)-(3-methyl)butanol + H2OS-(3-methylbutan-3-yl)-L-cysteinylglycine + L-glutamate (EC 3.4.19.13)
No genes
S-(3-methylbutan-3-yl)-L-cysteinylglycine + H2O→felinine + glycine (EC 3.4.13.23)
No genes
Cysteine-S-conjugate beta-lyase:
felinine→2-aminoprop-2-enoate + 3-methyl-3-sulfanylbutan-1-ol
(EC 4.4.1.13)
No genes
Tryptophanase:
2-aminoprop-2-enoate→2-iminopropanoate
(spontaneous) (EC 4.1.99.1; 4.1.99.2; 4.3.1.13; 4.3.1.17; 4.3.1.18; 4.3.3.8; 4.4.1.1; 4.4.1.13; 4.4.1.15; 4.4.1.25; 4.4.1.28; 4.4.1.35; 4.5.1.2)
PS417_05075 -0.1
PS417_01110 -0.0
PS417_12125 -3.2
PS417_22365 +0.2
PS417_26310 -0.3
2-iminopropanoate + H2O→pyruvate + ammonium (spontaneous) (EC 3.5.99.10; 4.1.99.1; 4.1.99.2; 4.3.1.13; 4.3.1.17; 4.3.1.18; 4.3.3.8; 4.4.1.1; 4.4.1.13; 4.4.1.15; 4.4.1.25; 4.4.1.28; 4.4.1.35; 4.5.1.2)
PS417_05075 -0.1
PS417_01110 -0.0
PS417_12125 -3.2
PS417_22365 +0.2
PS417_26310 -0.3
PS417_27835 -0.5

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information