MetaCyc Pathway: gallate degradation III (anaerobic) in Pseudomonas putida KT2440

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Reactions and Genes 1,3-Hexanediol (C)
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Gallate decarboxylase:
gallate + H+→pyrogallol + CO2 (EC 4.1.1.59)
No genes
Pyrogallol hydroxytransferase:
pyrogallol + 1,2,3,5-tetrahydroxybenzene→phloroglucinol + 1,2,3,5-tetrahydroxybenzene (EC 1.97.1.2)
No genes
Phloroglucinol reductase (in reverse):
phloroglucinol + NADPH + H+→dihydrophloroglucinol + NADP+ (EC 1.3.1.57)
No genes
dihydrophloroglucinol + H2O→3-hydroxy-5-oxohexanoate + H+
No genes
Acetate CoA-transferase (in reverse):
3-hydroxy-5-oxohexanoate + acetyl-CoA→acetate + 3-hydroxy-5-oxohexanoyl-CoA (EC 2.8.3.8)
No genes
3-hydroxy-5-oxohexanoyl-CoA + coenzyme A→acetyl-CoA + (S)-3-hydroxybutanoyl-CoA
No genes
(S)-3-hydroxybutanoyl-CoA→crotonyl-CoA + H2O (EC 4.2.1.150)
PP_1412 -0.0
PP_2047 +6.9
PP_2136 -3.7
PP_3726 +0.5
PP_3732 -0.1
crotonyl-CoA[cytosol] + 2 NADH[cytosol] + 2 an oxidized ferredoxin [iron-sulfur] cluster[cytosol]→butanoyl-CoA[cytosol] + 2 NAD+[cytosol] + 2 a reduced ferredoxin [iron-sulfur] cluster[cytosol] (EC 1.3.1.109)
No genes
Propionate CoA-transferase:
acetate + butanoyl-CoA→acetyl-CoA + butanoate (EC 2.8.3.1; 2.8.3.8)
No genes
Phosphate acetyltransferase:
acetyl-CoA + phosphate→acetyl phosphate + coenzyme A (EC 2.3.1.8)
PP_0774 -0.0
Acetate kinase (in reverse):
acetyl phosphate + ADP→acetate + ATP (EC 2.7.2.1; 2.7.2.15)
PP_1457 +0.0

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information