MetaCyc Pathway: petroselinate biosynthesis in Agrobacterium fabrum C58

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Reactions and Genes Melibiose (C)
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a palmitoyl-[acp] + dioxygen + 2 H+ + 2 a reduced ferredoxin [iron-sulfur] cluster→a (4Z)-hexadec-4-enoyl-[acp] + 2 an oxidized ferredoxin [iron-sulfur] cluster + 2 H2O (EC 1.14.19.11)
No genes
Beta-ketoacyl-acyl-carrier-protein synthase II:
a (4Z)-hexadec-4-enoyl-[acp] + a malonyl-[acp] + H+→a (6Z)-3-oxooctadec-6-enoyl-[acp] + a soluble [acyl-carrier protein] + CO2 (EC 2.3.1.179)
Atu1097 N.D.
Atu1596 N.D.
Atu1597 N.D.
Atu4216 +0.1
3-oxoacyl-[acyl-carrier-protein] reductase (in reverse):
a (6Z)-3-oxooctadec-6-enoyl-[acp] + NADPH + H+→a (3R,6Z)-3-hydroxyoctadec-6-enoyl-[acp] + NADP+ (EC 1.1.1.100)
Atu0705 -1.9
Atu0990 -0.0
Atu1095 N.D.
Atu1255 +0.3
Atu1338 +0.2
Atu2042 +0.2
Atu3051 -0.0
Atu3074 -0.1
Atu3333 +0.1
Atu3531 -0.1
Atu3813 -0.1
Atu4220 +0.1
Atu4325 +0.0
Atu4595 -0.1
Atu4821 -0.0
Atu4877 +0.2
Atu5122 -0.2
Atu5214 N.D.
Atu5250 N.D.
Atu5438 +0.0
a (3R,6Z)-3-hydroxyoctadec-6-enoyl-[acp]→a (2E,6Z)-octadecadienoyl-[acp] + H2O
No genes
a (2E,6Z)-octadecadienoyl-[acp] + NADPH + H+→a petroselinoyl-[acp] + NADP+
No genes
Oleoyl-[acyl-carrier-protein] hydrolase:
a petroselinoyl-[acp] + H2O→petroselinate + a soluble [acyl-carrier protein] + H+ (EC 3.1.2.14)
No genes

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information