MetaCyc Pathway: traumatin and (Z)-3-hexen-1-yl acetate biosynthesis in Agrobacterium fabrum C58
| Reactions and Genes | D-Arabinose (C) |
|---|---|
| remove | |
| Lipoxygenase: linoleate + dioxygen→(13S)-HPODE (EC 1.13.11.12) | |
| No genes | |
| Lipoxygenase: α-linolenate + dioxygen→13(S)-HpOTre (EC 1.13.11.12) | |
| No genes | |
| (13S)-HPODE→(9Z)-traumatin + 1-hexanal (EC 4.2.1.M17; 4.2.1.M19) | |
| No genes | |
| 13(S)-HpOTre→(9Z)-traumatin + (3Z)-hexenal (EC 4.2.1.M17; 4.2.1.M19) | |
| No genes | |
| (3Z)-hexenal→(E)-2-hexenal (spontaneous) | |
| No genes | |
| (3Z)-hexenal + NADH + H+→(3Z)-hex-3-en-1-ol + NAD+ | |
| No genes | |
| (9Z)-traumatin→traumatin | |
| No genes | |
| Lipoxygenase: (9Z)-traumatin + dioxygen→9-hydroperoxytraumatin (EC 1.13.11.12) | |
| No genes | |
| (3Z)-hex-3-en-1-ol + acetyl-CoA→(3Z)-hex-3-en-1-yl acetate + coenzyme A (EC 2.3.1.195) | |
| No genes | |
| Alcohol dehydrogenase (NADP(+)) (in reverse): (E)-2-hexenal + NADPH + H+→(E)-2-hexenol + NADP+ (EC 1.1.1.2) | |
| Atu2022 | -1.3 |
| (9Z)-traumatin + 9-hydroperoxytraumatin→9-hydroxy traumatin + 9,10-epoxy-12-oxododecanoate (EC 1.11.2.3) | |
| No genes | |
| 2 traumatin + dioxygen→2 traumatate + 2 H+ (spontaneous) | |
| No genes | |
Links:
Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information