MetaCyc Pathway: syringate degradation in Agrobacterium fabrum C58

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Reactions and Genes trans-aconitic (C)
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syringate + a tetrahydrofolate→3-O-methylgallate + a 5-methyltetrahydrofolate
No genes
3-O-methylgallate + dioxygen→2-pyrone-4,6-dicarboxylate + methanol + H+
No genes
3-O-methylgallate + dioxygen→4-carboxy-2-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate + H+
No genes
3-O-methylgallate + a tetrahydrofolate→gallate + a 5-methyltetrahydrofolate (EC 2.1.1.341)
No genes
gallate + dioxygen→(1E)-4-oxobut-1-ene-1,2,4-tricarboxylate + 2 H+ (EC 1.13.11.57)
No genes
4-carboxy-2-hydroxy-6-methoxy-6-oxohexa-2,4-dienoate + H2O→(1Z,3Z)-4-hydroxybuta-1,3-diene-1,2,4-tricarboxylate + methanol + H+
No genes
2-pyrone-4,6-dicarboxylate lactonase:
2-pyrone-4,6-dicarboxylate + H2O→(1E)-4-oxobut-1-ene-1,2,4-tricarboxylate + H+
(EC 3.1.1.57)
No genes
(1Z,3Z)-4-hydroxybuta-1,3-diene-1,2,4-tricarboxylate→(1E,3E)-4-hydroxybuta-1,3-diene-1,2,4-tricarboxylate (spontaneous)
No genes
(1E)-4-oxobut-1-ene-1,2,4-tricarboxylate→(1E,3E)-4-hydroxybuta-1,3-diene-1,2,4-tricarboxylate (spontaneous) (EC 5.3.2.8)
Atu4263 -2.1
4-oxalmesaconate hydratase (in reverse):
(1E,3E)-4-hydroxybuta-1,3-diene-1,2,4-tricarboxylate + H2O→2-hydroxy-4-oxobutane-1,2,4-tricarboxylate
(EC 4.2.1.83)
No genes
4-hydroxy-4-methyl-2-oxoglutarate aldolase:
2-hydroxy-4-oxobutane-1,2,4-tricarboxylate→oxaloacetate + pyruvate
(EC 4.1.3.17)
Atu4285 -0.2
Malate dehydrogenase (oxaloacetate-decarboxylating):
oxaloacetate + H+→pyruvate + CO2
(EC 1.1.1.38; 1.1.1.40; 1.1.1.83; 4.1.1.112)
Atu1652 N.D.
Atu3356 +0.0
Atu3402 +0.1

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Candidate genes for each reaction are identified from best hits to MetaCyc; by matching EC numbers (which are assigned by TIGRFam, SEED, or best hits to KEGG); or by matching SEED roles to KEGG reactions to MetaCyc reactions. See the "Protein" tab of each gene for more information